Segregation Behavior of Metal Impurities During Al-Si Melt Directional Solidification with an Open Ended Crucible

The distribution characteristic and segregation behavior of metal impurities during directional solidification of Al-20Si, Al-30Si and Al-40Si alloys have been investigated. The morphologies of the alloys and impurity phases were observed by optical microscopy, scanning electron microscopy and energy dispersive X-ray spectroscopy. The concentration profiles of representative metal impurities Al, Fe and Ti were measured by inductively coupled plasma optical emission spectrometry. The results indicate that the metal impurities segregate into the eutectic Al-Si melt during the growth of primary Si flakes and gradually segregate towards the top of each ingot during directional solidification. A concept of apparent segregation coefficient is proposed to characterize the segregation behavior of impurity elements. The apparent segregation coefficients of metal impurities decrease with increase in solidification temperature of the Al-Si alloys.     

Optimization of Preparation Conditions to Control Structural Characteristics of Silicon Dioxide Nanostructures Prepared by Magnetron Plasma Sputtering

In this work, highly-pure silicon oxide nanostructures were prepared by a closed-field unbalanced magnetron plasma sputtering technique. These nanostructures were characterized by Fourier-transform infrared spectroscopy, UV-visible spectroscopy, x-ray diffraction, scanning electron microscopy, energy-dispersive x-ray spectroscopy and atomic force microscopy in order to determine the optimum preparation conditions. Minimum particle size of 20 nm was determined for the samples prepared at an inter-electrode distance of 4 cm, Ar:O₂ gas mixing ratio of 70:30, total gas pressure of 0.08 torr, discharge voltage of 2.5 kV, discharge current of 35 mA, anode temperature of 27 ^°C (room temperature) and cathode temperature of about 40 ^°C. These conditions are optimized to control the structural characteristics of such nanostructures and hence to satisfy certain requirements and purposes in spectroscopic and photonic applications of SiO₂ nanostructures.     

Appraisal of Agriglass in Promoting Maize Production Under Abiotic Stress Conditions

An agriglass composition containing different oxides acts as a slow release for macro and micro nutrients and was chosen to improve maize yield under most important abiotic stresses which affecting agriculture development; salinity and drought. A field experiment was performed in salt affected soil (EC =?7.5 dSm^??1) by using different water deficit rates (I1 = 100, I2 = 85 and I3 = 70% of maize water requirements). Irrigation levels were located in main plots. Every main-plot divided into six sub-plots contained glassy fertilizer treatments [F1 = 55 kg fed^?1 with 1/2 mm diameter of agriglass (fed. =?4200 m²), F2 = 55 kg fed^?1 with 1 mm diameter, F3 = 80 kg fed^?1 with 1/2 mm diameter, F4 = 80 kg fed^?1 with 1 mm diameter, F5 = Recommendations of Ministry of Agriculture and F6 = control]. The experimental results demonstrated that, ears, straw, grains and biological yields increased with increasing both water and agriglass rates. Application of agriglass as a slow release fertilizer improved yield more than mineral fertilizer. Some growth parameters, water use efficiency (IWUE), macronutrients concentration and their relations were included. Other studies on residual effect of agriglass and the annual application rates to withstand salinity and drought stress by strategic crops are required.     

One-Pot,Three-Component Synthesis of 2,3-Dihydro-4(1H)-Quinazolinones Catalyzed by Perchlorated Zirconia (HClO<Subscript>4</Subscript>/ZrO<Subscript>2</Subscript>) Nanoparticles as a Solid Acid Catalyst

Mono and disubstituted 2,3-dihydroquinazolin-4(1H)-ones were obtained in good yields via a one-pot, three component reaction of isatoic anhydride and aromatic aldehydes with ammonium acetate or primary amines in the presence of perchlorated zirconia (HClO₄/ZrO₂) nano particles as an efficient solid acid catalyst under solvent-free conditions. Simple workup and reusability of the catalyst are advantages of this method.     

Mini Review on the Structure and Properties (Photocatalysis), and Preparation Techniques of Graphitic Carbon Nitride Nano-Based Particle,and Its Applications

Graphite carbon nitride (g-C₃N₄) is well known as one of the most promising materials for photocatalytic activities, such as CO₂ reduction and water splitting, and environmental remediation through the removal of organic pollutants. On the other hand, carbon nitride also pose outstanding properties and extensive application forecasts in the aspect of field emission properties. In this mini review, the novel structure, synthesis and preparation techniques of full-bodied g-C₃N₄-based composite and films were revealed. This mini review discussed contemporary advancement in the structure, synthesis, and diverse methods used for preparing g-C₃N₄ nanostructured materials. The present study gives an account of full knowledge of the use of the exceptional structural and properties, and the preparation techniques of graphite carbon nitride (g-C₃N₄) and its applications.     

Numerical and experimental study of conjugate heat transfer in a horizontal air cavity

The demand for general reduction of the energy consumption in civil engineering leads to more frequent use of insulating materials with air gaps or cavities. Heat transfer through a constructional part can be decreased by adding an air gap and low emissivity reflective foils to the structure. In the first part of this paper, the impacts of cavity thickness and inner surface emissivity on combined conduction, convection and radiation heat transfer was experimentally explored in the case of constructional part with a horizontal cavity subjected to constant downward heat flux. The heat flow meter Netzsch HFM 436 Lambda was used for steady-state measurements. Results suggest that the studied parameters seriously affect the combined heat transfer in the composed structure. In the second part the paper reports the numerical study of two-dimensional conjugate heat transfer in closed horizontal cavity having air as the intervening medium. Numerical models validated by related experimental results were performed to further investigate the effect of radiation heat transfer. It was found that in general, the total heat flux through the composed structure decreases with increasing air cavity thickness, which is significant especially when low emissivity inner surfaces are taking into account. The direction of heat flow (downward or upward heat flow) has a significant impact on the convection heat transfer. An important contribution from the present work is the analysis of the optimal thickness of the cavity at different boundary conditions. The optimal thickness of the enclosure with low emissivity surfaces is 16 mm when subjected to upward heat flux.     

Reducing undesirable vibrations of planar linkage mechanism with joint clearance

An optimization design method is presented to reduce the undesirable vibrations caused by clearance for planar linkage mechanism. A clearance joint is defined and considered a contact/impact force constraint. Contact and impact force models for the clearance joint are established using a normal contact force model based on Hertz model with energy loss and a tangential friction model based on modified Coulomb model with dynamic friction coefficient, respectively. In view of the clearance joint, dynamic equations and optimization method for a planar four-bar mechanism are then presented as an application example. The optimization aims to minimize the maximum absolute acceleration peaks of the mechanism by determining the link lengths of the planar linkage mechanism. Finally, the optimization design is solved by a generalized reduced gradient algorithm. Results show evident decrease in vibration peaks of the mechanism and obvious reduction in the contact forces in the clearance joint, which contribute to a good performance of planar linkage mechanism systems.     

新型格栅支撑有序堆积床内流动传热数值研究

颗粒堆积床作为反应器和分离器等的重要组成广泛应用于实际化学工业生产中。基于传统的有序堆积结构，提出了一种新型格栅支撑有序堆积结构，通过采用新型格栅支撑结构可以快速构建有序颗粒堆积床，其中包括格栅支撑简单立方、格栅支撑体心立方、格栅支撑疏松面心立方和格栅支撑密实面心立方颗粒堆积结构。对4种颗粒堆积单元通道内的流动换热进行模拟研究后发现，不同堆积形式的格栅支撑颗粒堆积床流动换热性能不同；在相同的面心立方堆积形式下，使用不同的格栅支撑结构，其流动传热也有明显差异；与传统有序堆积结构相比，在换热相差不多的情况下，格栅支撑有序堆积结构的压降减小，所以其综合换热效率有明显提升。